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Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
Published on: March 12, 2015
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A functionalized Ag₂S molecular architecture: facile assembly of the atomically precise ferrocene-decorated
Yiyi Liu1, Bahareh Khalili Najafabadi, Mahmood Azizpoor Fard
1Department of Chemistry, The University of Western Ontario, London, Ontario, N6A 5B7 (Canada).
Angewandte Chemie (International Ed. in English)
|February 24, 2015
Abstract:
A ferrocene-based dithiol 1,1'-[fc(C{O}OCH2CH2SH)2] has been prepared and treated with a Ag(I) salt to form the stable dithiolate compound [fc(C{O}OCH2CH2SAg)2]n (fc=[Fe(η(5)-C5H4)2]). This is used as a reagent for the preparation of the nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] which was obtained in good yield (dppp=1,3-bis(diphenylphosphino)propane).
