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Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
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A multicentre-bonded [Zn(I)]8 cluster with cubic aromaticity

Ping Cui1, Han-Shi Hu2, Bin Zhao1

  • 1Department of Chemistry, Key Laboratory of Advanced Energy Material Chemistry of the Ministry of Education, Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China.

Nature Communications
|February 24, 2015
PubMed
Summary

Researchers discovered novel polynuclear zinc clusters featuring zinc(I) ions and multicentered Zn-Zn bonds. These stable cubic clusters exhibit a new form of aromaticity, expanding metallic bonding concepts.

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