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Design freedom in multilayer thin-film devices
Carolyn R Ellinger1, Shelby F Nelson
1Eastman Kodak Company , 1999 Lake Avenue, Rochester, New York 14650, United States.
ACS Applied Materials & Interfaces
|February 24, 2015
Summary
A novel "patterned-by-printing" method enables fabrication of complex inorganic thin-film devices. This technique uses selective area deposition and atomic layer deposition for orthogonal patterning, overcoming limitations in traditional device manufacturing.
Area of Science:
- Materials Science
- Nanotechnology
- Device Fabrication
Background:
- Traditional thin-film device fabrication faces limitations due to material etch rates in inorganic systems and solvent compatibility in organic systems.
- Existing methods restrict multilayer structures and device design flexibility.
Purpose of the Study:
- To introduce a new fabrication method for high-quality metal oxide thin-film devices.
- To overcome processing constraints and enable greater design freedom in multilayer device architectures.
Main Methods:
- Utilizes a "patterned-by-printing" approach combining selective area deposition (SAD) and atomic layer deposition (ALD).
- Employs an inhibiting polymer ink to pattern functional inorganic materials deposited via spatial ALD (SALD).
- Achieves orthogonal patterning without etching or swelling of inorganic layers, defining isolation and vias through the printed inhibitor.
Main Results:
- Demonstrates inherently orthogonal patterning for additive fabrication of functional layers.
- Enables fabrication of diverse thin-film transistor architectures (bottom- and top-gate) on the same substrate.
- Successfully creates both all-enhancement-mode and enhancement-depletion-mode circuits.
- Presents a new tool for tuning circuit performance via local dielectric thickness control.
Conclusions:
- The patterned-by-printing method removes processing-related constraints, offering unprecedented freedom in device design.
- This additive patterning technique allows for flexible combinations of device components and architectures.
- The approach facilitates advanced circuit designs and performance tuning for thin-film electronic devices.

