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Updated: Apr 17, 2026

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries
Published on: November 10, 2014
Negligible "negative space-charge layer effects" at oxide-electrolyte/electrode interfaces of thin-film batteries
Masakazu Haruta1, Susumu Shiraki, Tohru Suzuki
1Advanced Institute for Material Research (AIMR), Tohoku University , 2-1-1 Katahira, Aoba, Sendai 980-8577, Japan.
Abstract:
In this paper, we report the surprisingly low electrolyte/electrode interface resistance of 8.6 Ω cm(2) observed in thin-film batteries. This value is an order of magnitude smaller than that presented in previous reports on all-solid-state lithium batteries. The value is also smaller than that found in a liquid electrolyte-based batteries. The low interface resistance indicates that the negative space-charge layer effects at the Li3PO(4-x)N(x)/LiCoO2 interface are negligible and demonstrates that it is possible to fabricate all-solid state batteries with faster charging/discharging properties.
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