An ionic liquid process for mercury removal from natural gas.
Mahpuzah Abai1, Martin P Atkins, Amiruddin Hassan
1PETRONAS Research Sdn. Bhd., Lot 3288 & 3289, Off Jalan Ayer Itam, Kawasan Institusi Bangi, 43000 Kajang, Selangor, Malaysia.
Dalton Transactions (Cambridge, England : 2003)
|February 28, 2015
Summary
Ionic liquids on solid supports efficiently remove mercury vapor from natural gas. This technology has been scaled up and successfully used in industrial petroleum gas production for three years.
Area of Science:
- Chemical Engineering
- Materials Science
Background:
- Mercury vapor in natural gas poses environmental and operational challenges.
- Effective mercury removal is crucial for the petroleum gas industry.
Purpose of the Study:
- To investigate the chemistry behind mercury vapor scrubbing using chlorocuprate(II) ionic liquids.
- To demonstrate the scalability of this technology from laboratory to industrial applications.
Main Methods:
- Utilizing chlorocuprate(II) ionic liquids impregnated on high surface area porous solid supports.
- Laboratory and industrial-scale testing of mercury vapor removal from natural gas streams.
Main Results:
- Achieved efficient scrubbing of mercury vapor in both laboratory and industrial settings.
- Demonstrated successful commercialization and continuous operation for three years in a Malaysian natural gas plant.
Conclusions:
- Chlorocuprate(II) ionic liquid-based materials are highly effective for mercury vapor removal from natural gas.
- The technology is scalable and proven for industrial application in the petroleum gas sector.
Related Concept Videos
High-Performance Liquid Chromatography: Elution Process
2.1K
In High-Performance Liquid Chromatography (HPLC), the elution process is critical to the separation of analytes and the quality of chromatographic results. Elution describes how compounds move through the column and separate based on their interactions with the mobile and stationary phases. This process determines the resolution, peak shape, and retention times in the chromatogram, which are essential for identifying and quantifying components in complex mixtures. Understanding the elution...
2.1K
Extraction: Advanced Methods
1.3K
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
1.3K
Oxymercuration-Reduction of Alkenes
10.1K
Oxymercuration–reduction of alkenes is one of the major reactions converting alkenes to alcohols. It involves the hydration of alkenes with mercuric acetate in a mixture of tetrahydrofuran and water, forming an organomercury adduct. This is followed by a demercuration step in which the adduct is reduced to an alcohol using sodium borohydride.
10.1K
The Joule and Joule–Thomson Experiments
186
Consider an adiabatic system composed of two chambers, A and B, designed such that no heat flows into or out of the system. Initially, chamber A is filled with a gas at a fixed temperature T1, pressure p1, and volume V1, while chamber B is evacuated. The gas is then gradually forced through a rigid, porous barrier to chamber B, ultimately reaching temperature T2, pressure p2, and volume V2. A piston on the right side maintains a constant pressure (p2), which is lower than p1. The significant...
186
Gas Chromatography: Introduction
5.0K
Gas chromatography (GC) is a technique for separating and analyzing volatile compounds in a sample. Its primary purpose is to identify and quantify components in complex mixtures, making it essential in fields such as environmental analysis, pharmaceuticals, and petrochemicals. GC is also called vapor-phase chromatography (VPC) or gas-liquid partition chromatography (GLPC).
In GC, a sample is vaporized and mixed with an inert carrier gas (the mobile phase), which transports it through a...
In GC, a sample is vaporized and mixed with an inert carrier gas (the mobile phase), which transports it through a...
5.0K
Sublimation
5.8K
Sublimation is the direct transformation of a solid to a gaseous state. For instance, at standard pressure and room temperature, solid carbon dioxide sublimes to gaseous carbon dioxide. The phase diagram depicts the conditions required for sublimation. This process occurs at the solid-gas phase boundary and is not observed above the triple point of the substance. The reverse of sublimation is called deposition, where a gaseous substance condenses directly into a solid. Sublimation and...
5.8K


