Related Experiment Video
Updated: Apr 16, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
New Phenomena in Organometallic-Mediated Radical Polymerization (OMRP) and Perspectives for Control of Less Active
1CNRS, LCC (Laboratoire de Chimie de Coordination) and Université de Toulouse, UPS, INPT, 205 route de Narbonne, BP 44099, 31077 Toulouse Cedex 4 (France); Institut Universitaire de France, 103 bd Saint-Michel, 75005 Paris (France). rinaldo.poli@lcc-toulouse.fr.
Abstract:
The impact of reversible bond formation between a growing radical chain and a metal complex (organometallic-mediated radical polymerization (OMRP) equilibrium) to generate an organometallic intermediate/dormant species is analyzed with emphasis on the interplay between this and other one-electron processes involving the metal complex, which include halogen transfer in atom transfer radical polymerization (ATRP), hydrogen-atom transfer in catalytic chain transfer (CCT), and catalytic radical termination (CRT). The challenges facing the controlled polymerization of "less active monomers" (LAMs) are outlined and, after reviewing the recent achievements of OMRP in this area, the perspectives of this technique are analyzed.
More Related Videos
Related Concept Videos
Radical Chain-Growth Polymerization: Overview
Free-Radical Chain Reaction and Polymerization of Alkenes
Radical Chain-Growth Polymerization: Mechanism
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Radical Reactivity: Overview
Radical Chain-Growth Polymerization: Chain Branching

