Related Experiment Video
Updated: Apr 16, 2026

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
Published on: January 26, 2016
Understanding the ideal glass transition: lessons from an equilibrium study of hard disks in a channel
1School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, United Kingdom.
Abstract:
We use an exact transfer-matrix approach to compute the equilibrium properties of a system of hard disks of diameter σ confined to a two-dimensional channel of width 1.95σ at constant longitudinal applied force. At this channel width, which is sufficient for next-nearest-neighbor disks to interact, the system is known to have a great many jammed states. Our calculations show that the longitudinal force (pressure) extrapolates to infinity at a well-defined packing fraction ϕ(K) that is less than the maximum possible ϕ(max), the latter corresponding to a buckled crystal. In this quasi-one-dimensional problem there is no question of there being any real divergence of the pressure at ϕ(K). We give arguments that this avoided phase transition is a structural feature, the remnant in our narrow channel system of the hexatic to crystal transition, but that it has the phenomenology of the (avoided) ideal glass transition. We identify a length scale ξ̃(3) as our equivalent of the penetration length for amorphous order: In the channel system, it reaches a maximum value of around 15σ at ϕ(K), which is larger than the penetration lengths that have been reported for three-dimensional systems. It is argued that the α-relaxation time would appear on extrapolation to diverge in a Vogel-Fulcher manner as the packing fraction approaches ϕ(K).
More Related Videos
08:55Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
06:26Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Related Concept Videos
Phase Transitions: Melting and Freezing
Recrystallization: Solid–Solution Equilibria
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Intermolecular Forces and Physical Properties
Liquid–Solid Solutions