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Reversible redox modulation of a lanthanide emissive molecular film
Joshua Lehr1, Manuel Tropiano, Paul D Beer
1Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3TA, United Kingdom. jason.davis@chem.ox.ac.uk.
Chemical Communications (Cambridge, England)
|March 17, 2015
Abstract:
Herein we demonstrate redox switchable emission from a sensitised, europium-ferrocene containing, molecular film assembled by a novel nitrene-based strategy. Electrochemical modulation of europium emission upon switching the ferrocene moiety's redox state is ascribed to the reversible generation of a quenching ferrocenium species.
