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Bio-inspired multinuclear copper complexes covalently immobilized on reduced graphene oxide as efficient
Yue-Ting Xi1, Ping-Jie Wei, Ru-Chun Wang
1Key Laboratory for Advanced Materials of MOE & Department of Chemistry, East China University of Science and Technology, Shanghai, 200237, P. R. China. liujingang@ecust.edu.cn.
Abstract:
Inspired by the multicopper active site of laccase, which efficiently catalyzes the oxygen reduction reaction (ORR), herein we report a novel bio-inspired ORR catalyst composed of a multinuclear copper complex that was immobilized on the surface of reduced graphene oxide (rGO) via the covalently grafted triazole-dipyridine (TADPy) dinucleating ligand. This rGO-TADPyCu catalyst exhibited high ORR activity and superior long-term stability compared to Pt/C in alkaline media.
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