Related Experiment Videos
How many digits should be reported in forensic breath alcohol measurements?
1Clearview Statistical Consulting, 20119 61st Avenue SE, Snohomish, WA 98296, USA rod.gullberg@gmail.com.
Journal of Analytical Toxicology
|April 2, 2015
Summary
Reporting three digits in breath alcohol measurements is more accurate than two. This provides a more precise uncertainty value, improving the reliability of forensic analysis results.
Area of Science:
- Analytical Chemistry
- Forensic Science
- Measurement Science
Background:
- Measurement results inherently contain uncertainty.
- The number of reported digits should reflect this uncertainty.
- Current practices in breath alcohol analysis may not be optimal.
Purpose of the Study:
- To evaluate the appropriate number of digits for reporting breath alcohol measurements.
- To compare the uncertainty associated with two-digit versus three-digit results.
- To advocate for evidence-based reporting practices in forensic analysis.
Main Methods:
- Statistical analysis of measurement uncertainty.
- Comparison of combined uncertainty for two- and three-digit truncated results.
- Review of historical practices in breath alcohol analysis.
Main Results:
- The first significant digit of combined uncertainty in breath alcohol measurement appears in the third decimal place.
- Reporting three digits significantly reduces combined uncertainty compared to two digits.
- For a breath alcohol concentration of 0.089 g/210 L, three-digit results yield a combined uncertainty of 0.0031 g/210 L, versus 0.0042 g/210 L for two-digit results.
Conclusions:
- Three-digit truncated results are statistically more appropriate for breath alcohol measurements.
- Modern digital instrumentation supports more precise reporting than historical analog devices.
- The principles discussed are applicable to other quantitative analytical measurements.
Related Concept Videos
Uncertainty in Measurement: Reading Instruments
49.7K
Counting is the type of measurement that is free from uncertainty, provided the number of objects being counted does not change during the process. Such measurements result in exact numbers. By counting the eggs in a carton, for instance, one can determine exactly how many eggs are there in the carton. Similarly, the numbers of defined quantities are also exact. For example, 1 foot is exactly 12 inches, 1 inch is exactly 2.54 centimeters, and 1 gram is exactly 0.001 kilograms. Quantities...
49.7K
Rules for Significant Figures
33.6K
In any measurement, the precision of the measuring tool is an essential factor. An ordinary ruler, for example, can measure length to the closest millimeter; a caliper, on the other hand, can measure length to the nearest 0.01 mm. As a result, the caliper is a more precise measurement tool because it can measure extremely minute changes in length. The measurements will be more accurate if the measuring tool is more precise.
It should be emphasized that when we represent measured values, the...
It should be emphasized that when we represent measured values, the...
33.6K
Uncertainty in Measurement: Significant Figures
79.4K
All the digits in a measurement, including the uncertain last digit, are called significant figures or significant digits. Note that zero may be a measured value; for example, if a scale that shows weight to the nearest pound reads “140,” then the 1 (hundreds), 4 (tens), and 0 (ones) are all significant (measured) values.
79.4K
Mass Spectrometry: Alcohol Fragmentation
4.3K
Alcohols (R-OH) ionize to lose one non-bonded electron from the oxygen atom, forming molecular ions. Due to their tendency to fragment rapidly, the intensity of the molecular ion peak in the mass spectrum is weak or sometimes absent. The fragmentation patterns for alcohols occur in two ways, i.e. ⍺-cleavage and dehydration. During ⍺-cleavage, the bond at the ⍺-position adjacent to the hydroxyl group cleaves to give a resonance-stabilized cation and a radical. However, intramolecular...
4.3K
Special considerations while measuring oxygen saturation
853
Assessing respiratory rate concurrently with pulse measurement is fundamental to patient care, providing valuable insights into the patient's respiratory function. The normal breathing rate for an adult usually falls within a normal range of 12 to 20 breaths per minute. Abnormal respiratory rates can signal underlying health conditions or the need for immediate intervention.
Ensuring accuracy in vital sign recordings while prioritizing patient comfort and minimizing anxiety is...
Ensuring accuracy in vital sign recordings while prioritizing patient comfort and minimizing anxiety is...
853
Significant Figures in Calculations
16.1K
Uncertainty in measurements can be avoided by reporting the results of a calculation with the correct number of significant figures. This can be determined by the following rules for rounding numbers:
16.1K