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Updated: Apr 15, 2026
Ligand-Mediated Nucleation and Growth of Palladium Metal Nanoparticles
Published on: June 25, 2018
Facile hydrolysis and alcoholysis of palladium acetate
Robin B Bedford1, John G Bowen2, Russell B Davidson2
1School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS (UK). r.bedford@bristol.ac.uk.
Abstract:
Palladium(II) acetate is readily converted into [Pd3 (μ(2) -OH)(OAc)5 ] (1) in the presence of water in a range of organic solvents and is also slowly converted in the solid state. Complex 1 can also be formed in nominally anhydrous solvents. Similarly, the analogous alkoxide complexes [Pd3 (μ(2) -OR)(OAc)5 ] (3) are easily formed in solutions of palladium(II) acetate containing a range of alcohols. An examination of a representative Wacker-type oxidation shows that the Pd-OH complex 1 and a related Pd-oxo complex 4 can be excluded as potential catalytic intermediates in the absence of exogenous water.
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