Related Experiment Video
Updated: Apr 15, 2026

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
Published on: April 12, 2019
Critical Casimir force in the presence of random local adsorption preference
1Institut für Theoretische Physik und Astrophysik, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany.
Abstract:
We study the critical Casimir force for a film geometry in the Ising universality class. We employ a homogeneous adsorption preference on one of the confining surfaces, while the opposing surface exhibits quenched random disorder, leading to a random local adsorption preference. Disorder is characterized by a parameter p, which measures, on average, the portion of the surface that prefers one component, so that p=0,1 correspond to homogeneous adsorption preference. By means of Monte Carlo simulations of an improved Hamiltonian and finite-size scaling analysis, we determine the critical Casimir force. We show that by tuning the disorder parameter p, the system exhibits a crossover between an attractive and a repulsive force. At p=1/2, disorder allows to effectively realize Dirichlet boundary conditions, which are generically not accessible in classical fluids. Our results are relevant for the experimental realizations of the critical Casimir force in binary liquid mixtures.
Related Concept Videos
Adsorption Isotherms I
Adsorption Isotherms II
Adsorption of Gases on Solids
Noncovalent Attractions in Biomolecules
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Noncovalent Attractions in Biomolecules
Intermolecular Forces

