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Operation of a 25 KWth Calcium Looping Pilot-plant with High Oxygen Concentrations in the Calciner
Published on: October 25, 2017
Chemical Looping Technology: Oxygen Carrier Characteristics
Siwei Luo1, Liang Zeng, Liang-Shih Fan
1William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, Columbus, Ohio 43210; email: luo.92@osu.edu , zeng.40@osu.edu , fan.1@osu.edu.
Chemical looping processes offer efficient carbonaceous fuel conversion with CO2 capture. This review analyzes chemical looping full oxidation (CLFO) and chemical looping partial oxidation (CLPO), focusing on oxygen carriers for optimal configurations.
Area of Science:
- Chemical Engineering
- Energy Conversion
- Carbon Capture Technologies
Background:
- Chemical looping processes are advanced methods for converting carbonaceous fuels.
- These technologies are recognized for efficient energy conversion and effective CO2 capture.
- Two primary types exist: chemical looping full oxidation (CLFO) and chemical looping partial oxidation (CLPO).
Purpose of the Study:
- To review and analyze advancements in chemical looping technologies.
- To specifically examine developments in oxygen carriers crucial for these processes.
- To compare and contrast CLFO and CLPO, highlighting differences in configurations and carriers.
Main Methods:
- Literature review and analysis of existing research on CLFO and CLPO.
- Focus on the role and development of oxygen carriers in chemical looping systems.
- Comparative study of process configurations for different chemical looping applications.
Main Results:
- CLFO, exemplified by chemical looping combustion, produces CO2 and H2O for electricity generation.
- CLPO, such as chemical looping gasification, yields syngas or hydrogen.
- Significant variations exist in optimal process configurations and oxygen carrier selection between CLFO and CLPO.
Conclusions:
- Chemical looping offers a promising pathway for sustainable fuel conversion with integrated CO2 management.
- Oxygen carrier development is a key factor differentiating and optimizing CLFO and CLPO.
- Further research into specific oxygen carriers can enhance the efficiency and applicability of both CLFO and CLPO.
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