Tetralithiated tetraazaperopyrene as a key intermediate for the synthesis of functionalized derivatives
Lena Hahn1, Hubert Wadepohl1, Lutz H Gade1
1Anorganisch-Chemisches-Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Abstract:
A new synthetic approach to core-functionalized tetraazaperopyrenes (TAPP) is reported. In-situ reaction of 4-fold lithiated TAPP with electrophiles results in the formation of various unprecedented TAPP derivatives, which are highly emissive fluorophores, show promising photophysical and electrochemical properties and act as valuable starting materials. Thus, lithiation of the TAPP core opens up a facile way for developing new organic materials.
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