Related Experiment Video
Updated: Apr 14, 2026

Ultrafast Time-resolved Near-IR Stimulated Raman Measurements of Functional π-conjugate Systems
Published on: February 10, 2020
State-resolved collisional relaxation of highly vibrationally excited CsH by CO2
Baoxia Mu1, Xiuhua Cui2, Yifan Shen2
1School of Science, Xi'an Jiaotong University, Xi'an 710049, China; Department of Physics, Xinjiang University, Urumqi 830046, China.
Abstract:
Quenching of highly vibrationally excited CsH(X(1)Σ(+), v=15-23) by collisions with CO2 was investigated. A significant fraction of the initial population of highly vibrationally excited CsH(v=22) was relaxed to a low vibrational level (Δv=-5). The near-resonant 5-1 vibration-to-vibration (V-V) energy was efficiently exchanged. The rate constants for the rotational levels of CO2(00(0)0) [J=36-60] and CO2(00(0)1) [J=5-31] from the collisions with excited CsH were determined. The experiments revealed that the collisions resulting in CO2(00(0)0) were accompanied by substantial excitation in rotation and translation. The vibrationally excited CO2(00(0)1) state exhibited rotational and translational energy distributions near those of the initial state. The total quenching rates relative to the probed state of excited CsH were determined for both CO2 states. The corresponding data indicated that the gains in the rotational and translational energies in CO2 were sensitive to the collisional depletion of excited CsH.
Related Concept Videos
Double Resonance Techniques: Overview
Spin decoupling is usually achieved by...
¹³C NMR: ¹H–¹³C Decoupling
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers...
2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)
Atomic Nuclei: Nuclear Relaxation Processes

