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Related Concept Videos

Phase Diagrams of Ternary Systems01:28

Phase Diagrams of Ternary Systems

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Consider a ternary system, which is composed of three components: water (W), ethanoic acid (E), and trichloromethane (T). Here, Ethanoic acid (E) is fully miscible with both water (W) and trichloromethane (T), meaning it can mix entirely with either of them. However, water and trichloromethane have partial miscibility, meaning they can only mix to a certain extent, beyond which two separate phases will form.The phase diagram of a ternary system is represented as an equilateral triangle, where...
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The temperature-composition phase diagram of two solids, A and B, which are immiscible in the solid phase but form miscible liquids, shows that when the temperature is low, these two exist as separate, pure solids (A and B). As the temperature increases, they transition into a single-phase liquid solution where A and B coexist. Moving from point a1 to a2 in the phase diagram, the composition changes such that solid B begins to separate from the solution, enriching the remaining liquid with A.
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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
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A phase transition is the process in which a substance changes from one state of matter to another, like from a solid to a liquid, liquid to gas, or vice versa, at a specific temperature and under given pressure conditions. This change is spontaneous and is affected by alterations in temperature and pressure. These parameters impact the strength of the forces between molecules (intermolecular forces) in the substance.During a phase transition, both the initial and final phases of the substance...
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Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
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Related Experiment Video

Updated: Apr 13, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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More statistics on intermetallic compounds - ternary phases.

Julia Dshemuchadse1, Walter Steurer1

  • 1Laboratory of Crystallography, Department of Materials, ETH Zurich, Zurich, Switzerland.

Acta Crystallographica. Section A, Foundations and Advances
|April 30, 2015
PubMed
Summary
This summary is machine-generated.

This statistical analysis of intermetallic compounds reveals insights into their structure types and chemical compositions. It highlights the uniqueness of certain ternary structures and the limited exploration of possible ternary systems.

Keywords:
compositionscrystal-structure statisticsintermetallicsstructure typesternary compounds

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Area of Science:

  • Materials Science
  • Crystallography
  • Chemical Physics

Background:

  • Intermetallic compounds are crucial in materials science, exhibiting diverse crystal structures and chemical compositions.
  • Understanding their ordering principles is key to discovering new materials with desired properties.
  • Pearson's Crystal Data provides a comprehensive database for such analyses.

Purpose of the Study:

  • To statistically analyze the structures of known intermetallic compounds.
  • To investigate the diversity of structure types and chemical compositions among intermetallics.
  • To gain insights into the ordering principles governing intermetallic structures, focusing on ternary systems.

Main Methods:

  • Statistical analysis of 20,829 intermetallic phases from Pearson's Crystal Data.
  • Focus on a subset of 13,026 ternary intermetallics.
  • Utilizing structure maps with Mendeleev numbers as ordering parameters for chemical composition analysis.

Main Results:

  • Identified 1391 different structure types for ternary intermetallics.
  • Found 667 ternary structure types with only one representative, indicating unique structural characteristics.
  • Observed that ternary compounds are known for only 5109 out of 85,320 theoretically possible ternary systems.

Conclusions:

  • The study provides a statistical overview of intermetallic compound structures and compositions.
  • Unique ternary structure types warrant further investigation into their formation principles.
  • Significant potential exists for discovering new ternary intermetallic compounds within unexplored systems.