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Updated: Apr 13, 2026

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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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A structure-directing method to prepare semiconductive zeolitic cluster-organic frameworks with Cu3I4 building units
Yao Kang1, Wei-Hui Fang, Lei Zhang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. LZhang@fjirsm.ac.cn.
Abstract:
Two semiconductive cluster-organic frameworks based on Cu4I4 and Cu3I4 building units were obtained by the use of different organic structure-directing agents; the latter Cu3I4 nodes are tetrahedrally connected through 1,4-diazabicyclo[2.2.2]octane (DABCO) linkers and Cu-I bridges, giving rise to a zeolitic framework with SOD topology.

