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Updated: Apr 12, 2026

Fabrication of Periodic Gold Nanocup Arrays Using Colloidal Lithography
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Controllable Tuning Plasmonic Coupling with Nanoscale Oxidation.

Tao Ding1, Daniel Sigle1, Liwu Zhang1

  • 1Nanophotonics Centre, Cavendish Laboratory, University of Cambridge, Cambridge CB3 0HE, U.K.

ACS Nano
|May 16, 2015
PubMed
Summary
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Researchers developed a new method to precisely control nanoparticle on mirror (NPoM) gap sizes for enhanced plasmonic coupling. This technique enables tunable optical properties for advanced applications.

Area of Science:

  • Nanophotonics
  • Plasmonics
  • Materials Science

Background:

  • Nanoparticle on mirror (NPoM) constructs offer strong localized plasmon coupling.
  • Controlling gap sizes and tunability in NPoMs is challenging compared to nanoparticle dimers.

Purpose of the Study:

  • To develop a facile and controllable method for fabricating NPoMs with tunable plasmonic coupling.
  • To investigate the effect of controlled oxide layer thickness on plasmon resonance in NPoMs.

Main Methods:

  • Utilized reactive metals (e.g., Aluminum) as mirrors to form controllable metal oxide spacing layers.
  • Employed various oxidation techniques: electrochemical, thermal annealing, oxygen plasma, and laser photo-oxidation.
  • Calibrated oxide layer thickness using depth-mode X-ray photoemission spectroscopy (XPS).
Keywords:
aluminumelectrochemistryirradiationoxidizationplasmons

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Main Results:

  • Achieved continuous tuning of plasmonic coupling by controlling oxide layer thickness.
  • Observed a blue-shift in the plasmonic resonance peak with increasing oxide thickness, while the transverse mode remained constant.
  • Simulations accurately matched experimental observations.

Conclusions:

  • The proposed method allows for scalable, local, and controllable fabrication of NPoMs with tailored plasmonic coupling.
  • This approach is suitable for diverse applications including sensing, photochemistry, photoemission, and photovoltaics.