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High Performance and Long-Term Stability in Ambiently Fabricated Segmented Solid-State Polymer Electrochromic
Julian Remmele1, D Eric Shen2, Tero Mustonen2
1†Institute for Large Area Microelectronics, University of Stuttgart, 70569 Stuttgart, Germany.
ACS Applied Materials & Interfaces
|May 16, 2015
Summary
This study presents a stable, high-contrast polymer electrochromic display (PED) using solution-based methods. The device exceeds 100,000 cycles, demonstrating potential for low-power electronic applications.
Area of Science:
- Materials Science
- Polymer Science
- Display Technology
Background:
- Polymer electrochromic displays (PEDs) offer low power consumption and high contrast.
- Developing stable and efficient PEDs for practical applications remains a challenge.
Purpose of the Study:
- To report the performance of a segmented PED fabricated using solution-based processes.
- To investigate asymmetric driving and analyze degradation effects for enhanced stability.
- To demonstrate a functional clock application showcasing the display's capabilities.
Main Methods:
- Fabrication of a segmented PED using solution-based processes in ambient atmosphere.
- Implementation of an encapsulation process and structured wells for active layers.
- Utilizing a preoxidized counter polymer for improved performance.
- Investigating asymmetric driving and analyzing electrochrome degradation.
- Integrating a printed circuit board for clock functionality.
Main Results:
- Achieved high contrast ratios and fast switching speeds.
- Demonstrated device stability exceeding 100,000 switching cycles.
- Successfully operated the display as a low-power clock using short switching pulses.
- Identified and addressed degradation effects in the electrochrome layer.
Conclusions:
- Solution-based fabrication offers a viable route for high-performance PEDs.
- The developed display exhibits excellent stability and low power requirements.
- This technology shows promise for advanced, low-power electronic devices like clocks.

