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Updated: Apr 12, 2026

Ultrafast Time-resolved Near-IR Stimulated Raman Measurements of Functional π-conjugate Systems
Published on: February 10, 2020
Communication: Saturated CO2 absorption near 1.6 μm for kilohertz-accuracy transition frequencies
Johannes Burkart1, Tommaso Sala2, Daniele Romanini1
1Univ. Grenoble Alpes, LIPhy, F-38000 Grenoble, France.
Abstract:
Doppler-free saturated-absorption Lamb dips were measured on weak rovibrational lines of (12)C(16)O2 between 6189 and 6215 cm(-1) at sub-Pa pressures using optical feedback frequency stabilized cavity ring-down spectroscopy. By referencing the laser source to an optical frequency comb, transition frequencies for ten lines of the 30013←00001 band P-branch and two lines of the 31113←01101 hot band R-branch were determined with an accuracy of a few parts in 10(11). Involving rotational quantum numbers up to 42, the data were used for improving the upper level spectroscopic constants. These results provide a highly accurate reference frequency grid over the spectral interval from 1599 to 1616 nm.
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