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Published on: August 10, 2016
Enhancing hemicelluloses removal from a softwood sulfite pulp
Jianguo Li1, Hongjie Zhang2, Chao Duan1
1Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin 300457, China; Limerick Pulp and Paper Centre, Department of Chemical Engineering, University of New Brunswick, Fredericton, New Brunswick E3B 5A3, Canada.
This study shows that sequential pulp fractionation and caustic treatment effectively remove hemicelluloses from softwood sulfite pulp. Long fibers are more amenable to hemicellulose removal via cold caustic extraction (CCE) and hot caustic extraction (HCE).
Area of Science:
- Biomass processing
- Pulp and paper science
- Biochemical engineering
Background:
- Hemicelluloses removal is crucial for biomass bioconversion and high-quality dissolving pulp production.
- Softwood sulfite pulp requires efficient pretreatment methods for industrial applications.
Purpose of the Study:
- To investigate a sequential treatment for hemicelluloses removal from softwood sulfite pulp.
- To compare the effectiveness of cold caustic extraction (CCE) and hot caustic extraction (HCE) on different fiber fractions.
Main Methods:
- Pulp fractionation to separate long and short fiber fractions.
- Sequential treatment involving cold caustic extraction (CCE) and hot caustic extraction (HCE).
- Analysis of hemicelluloses content, specific surface area, pore diameter, selectivity, and yield.
Main Results:
- Long-fiber fraction exhibited lower hemicelluloses content and smaller specific surface area but larger pore diameter than the short-fiber fraction.
- Hemicelluloses removal was more effective in the long-fiber fraction compared to the short-fiber fraction under both CCE and HCE conditions.
- Hemicelluloses removal selectivity and pulp yield were also evaluated for both fiber fractions and treatment methods.
Conclusions:
- Sequential pulp fractionation followed by caustic extraction is an effective strategy for hemicelluloses removal from softwood sulfite pulp.
- The long-fiber fraction is more responsive to hemicelluloses removal via CCE and HCE, offering potential for optimized pulp processing.
- Understanding fiber characteristics is key to enhancing hemicelluloses removal efficiency in biomass pretreatment.
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