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Attenuated Organomagnesium Activation of White Phosphorus
Merle Arrowsmith1, Michael S Hill2, Andrew L Johnson1
1Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK).
Angewandte Chemie (International Ed. in English)
|May 28, 2015
Abstract:
Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P4 allow the highly discriminating synthesis of unusual [nBu2P4](2-) and [nBu2P8](2-) cluster dianions.