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Published on: April 1, 2018
Mechanically Robust and Self-Healable Superlattice Nanocomposites by Self-Assembly of Single-Component "Sticky"
Gregory A Williams1, Ryohei Ishige2, Olivia R Cromwell1
1Department of Chemistry, 1102 Natural Sciences 2, University of California, Irvine, CA, 92697, USA.
Abstract:
A simple, scalable synthesis of mechanically robust and self-healable superlattice nanocomposites is achieved through self-assembly of single-component "sticky" polymer-grafted nanoparticles. The multi-valent hydrogen-bonding interactions between the nanoparticles provide strong cohesive energy, binding the nanoparticles into strong and tough materials. Furthermore, the dynamic hydrogen-bonding interactions afford the formation of highly dynamic, self-healing, and mechanochromic nanocomposite materials in the bulk.

