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Synthesis and Ligand Exchange of Thiol-Capped Silicon Nanocrystals

Yixuan Yu1, Clare E Rowland2,3, Richard D Schaller2,3

  • 1†McKetta Department of Chemical Engineering, Texas Materials Institute, and Center for Nano- and Molecular Science and Technology, The University of Texas at Austin, Austin, Texas 78712-1062, United States.

Langmuir : the ACS Journal of Surfaces and Colloids
|May 30, 2015
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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