Porphyrinic supramolecular daisy chains incorporating pillar[5]arene-viologen host-guest interactions
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Updated: Apr 11, 2026

Self-Assembly of Gamma-Modified Peptide Nucleic Acids into Complex Nanostructures in Organic Solvent Mixtures
Published on: June 26, 2020
Maher Fathalla1, Nathan L Strutt, Srinivasan Sampath
1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. stoddart@northwestern.edu.
Abstract:
A porphyrin functionalised with pillar[5]arene and a viologen at its 5- and 15-meso positions assembles in a head-to-tail manner, producing linear supramolecular daisy chains in dichloromethane. At high concentrations, it forms an organogel which has been investigated by electron microscopy and rheological measurements, paving the way for the preparation of other functional supramolecular assemblies which harness viologen⊂pillararene host-guest interactions.
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