(Fe,Co)@nitrogen-doped graphitic carbon nanocubes derived from polydopamine-encapsulated metal-organic frameworks as a highly stable and selective non-precious oxygen reduction electrocatalyst
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A Salt-Templated Synthesis Method for Porous Platinum-based Macrobeams and Macrotubes
Published on: May 18, 2020
Jiangbo Xi1, Yating Xia, Yangyang Xu
1Key Laboratory for Large-Format Battery Materials and System, Ministry of Education, Department of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, Wuhan, P. R. China. chjwxiao@hust.edu.cn chmsamuel@hust.edu.cn.
Abstract:
A facile approach is reported to synthesize (Fe,Co)@nitrogen-doped graphitic carbon (NGC) nanocubes (NCs) via the pyrolysis of polydopamine-encapsulated Fe3[Co(CN)6]2 NCs at 700 °C. Besides the comparable catalytic activity for oxygen reduction reaction (ORR) to the Pt/C catalyst, it showed much more outstanding catalytic selectivity and superior durability.

