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Updated: Apr 11, 2026

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
Published on: January 19, 2018
How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential
Màrius Tarrés1, Víctor S Arderiu, Adnana Zaulet
1Institut de Ciencia de Materials de Barcelona, ICMAB-CSIC, Campus UAB, E-08193 Bellaterra, Spain. teixidor@icmab.es.
Abstract:
An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV](2+)) has been used as a benchmark.
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