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Updated: Apr 10, 2026

Hollow Microneedle-based Sensor for Multiplexed Transdermal Electrochemical Sensing
Published on: June 1, 2012
Hybrid organic-inorganic porous semiconductor transducer for multi-parameters sensing
Alessandro Caliò1, Antonio Cassinese2, Maurizio Casalino3
1IMM-CNR, Via P. Castellino 111, Naples 80131, Italy Department of Physics, University of Naples 'Federico II', Via Cinthia, Naples 80100, Italy.
Abstract:
Porous silicon (PSi) non-symmetric multi-layers are modified by organic molecular beam deposition of an organic semiconductor, namely the N,N'-1H,1H-perfluorobutyldicyanoperylene-carboxydi-imide (PDIF-CN2). Joule evaporation of PDIF-CN2 into the PSi sponge-like matrix not only improves but also adds transducing skills, making this solid-state device a dual signal sensor for chemical monitoring. PDIF-CN2 modified PSi optical microcavities show an increase of about five orders of magnitude in electric current with respect to the same bare device. This feature can be used to sense volatile substances. PDIF-CN2 also improves chemical resistance of PSi against alkaline and acid corrosion.

