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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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High-resolution Thermal Micro-imaging Using Europium Chelate Luminescent Coatings
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Thickness dependent terahertz emission from cobalt thin films.

Nishant Kumar, Ruud W A Hendrikx, Aurèle J L Adam

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    |June 16, 2015
    PubMed
    Summary

    Femtosecond laser pulses generate terahertz (THz) emission from cobalt films. Film thickness dictates whether THz emission depends on in-plane or out-of-plane magnetization, impacting its directionality.

    Area of Science:

    • Condensed Matter Physics
    • Materials Science
    • Ultrafast Optics

    Background:

    • Terahertz (THz) pulse emission from magnetic materials is a key phenomenon in spintronics and ultrafast magnetism.
    • Understanding the relationship between film properties and THz emission characteristics is crucial for developing novel THz sources and devices.
    • Cobalt thin films are promising candidates for such applications due to their magnetic properties.

    Purpose of the Study:

    • To investigate the influence of cobalt thin film thickness on terahertz (THz) pulse emission characteristics.
    • To determine the role of in-plane versus out-of-plane magnetization components in THz emission.
    • To correlate magnetic properties with observed THz emission phenomena.

    Main Methods:

    • Illumination of cobalt thin films with femtosecond laser pulses.

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  • Detection and analysis of emitted terahertz (THz) pulses.
  • Rotation of the sample about the surface normal to study azimuthal angle dependence.
  • Magnetic force microscopy (MFM) to characterize film magnetization.
  • Main Results:

    • For cobalt films < 40 nm, THz electric field direction rotates with sample rotation (azimuthal angle-dependent), indicating in-plane magnetization influence.
    • For thicker films (> 40 nm), an azimuthal angle-independent THz emission component emerges, attributed to out-of-plane magnetization.
    • The contribution of the out-of-plane magnetization component to THz emission increases with film thickness.

    Conclusions:

    • Cobalt thin film thickness is a critical parameter controlling the nature of laser-induced THz emission.
    • The transition from in-plane to out-of-plane magnetization dominance with increasing thickness directly impacts THz emission anisotropy.
    • These findings provide insights into the mechanisms of THz generation in magnetic thin films and guide material design for tailored THz emission.