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Updated: Apr 8, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Circularly polarized luminescence under near-UV excitation and structural elucidation of a Eu complex
Francesco Zinna1, Claudio Resta, Sergio Abbate
1Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 13, I-56126, Pisa, Italy. lorenzo.dibari@unipi.it.
Abstract:
A new chiral diketonate ligand based on carvone binds early lanthanides. The Eu complex displays high circularly polarized (g(lum) = 0.82) red luminescence under near-UV excitation in the solid state. This is the first report on such CPL activity in the solid state with a rigorous protocol to exclude artifacts. Paramagnetic NMR spectroscopy revealed the nature and structure of the active species.
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