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Updated: Apr 7, 2026

Influence of Hybrid Perovskite Fabrication Methods on Film Formation, Electronic Structure, and Solar Cell Performance
Published on: February 27, 2017
Transparent conductive oxide-free perovskite solar cells with PEDOT:PSS as transparent electrode
Kuan Sun1, Pengcheng Li, Yijie Xia
1‡School of Power Engineering, Chongqing University, 174 Shazhengjie, Shapingba, Chongqing 400044, China.
Abstract:
Perovskite solar cells (PSCs) have been attracting considerable attention because of their low fabrication cost and impressive energy conversion efficiency. Most PSCs are built on transparent conductive oxides (TCOs) such as fluorine-doped tin oxide (FTO) or indium tin oxide (ITO), which are costly and rigid. Therefore, it is significant to explore alternative materials as the transparent electrode of PSCs. In this study, highly conductive and highly transparent poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (
Pedot:
PSS) films were investigated as the transparent electrode of both rigid and flexible PSCs. The conductivity of
Pedot:
PSS films on rigid glass or flexible poly(ethylene terephthalate) (PET) substrate is significantly enhanced through a treatment with methanesulfonic acid (MSA). The optimal power conversion efficiency (PCE) is close to 11% for the rigid PSCs with an MSA-treated
Pedot:
PSS film as the transparent electrode on glass, and it is more than 8% for the flexible PSCs with a MSA-treated
Pedot:
PSS film as the transparent electrode on PET. The flexible PSCs exhibit excellent mechanical flexibility in the bending test.

