Related Experiment Videos
Protonation effect on ligands in EuL: a luminescent switcher for fast naked-eye detection of HCl
Jun Zhang1, Wen-Bin Yang, Xiao-Yuan Wu
1Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou, Fujian 350002, China. czlu@fjirsm.ac.cn.
Abstract:
A new luminescent coordination polymer, EuH(L)(2)(NO(3))(2) (EuL, HL = 2-(2-pyridin-2-yl)quinoline-4-carboxylic acid), has been solvothermally synthesized, and its framework of uncoordinated pyridyl rings was exploited for the binding and specific sensing of HCl via a protonation effect. The protonation effect changes the energy of the excited state of the ligands, rendering them unable to act as efficient antennae for Eu(3+) characteristic emission. Thus, we have developed a new, fast and convenient sensor for HCl, a gas harmful for the environment.