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Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity
Martin Lammert1, Michael T Wharmby, Simon Smolders
1Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, 24118 Kiel, Germany. stock@ac.uni-kiel.de.
Chemical Communications (Cambridge, England)
|July 9, 2015
Abstract:
A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.
