High-performance PdNi alloy structured in situ on monolithic metal foam for coalbed methane deoxygenation via
Qiaofei Zhang1, Xin-Ping Wu, Guofeng Zhao
1Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, P. R. China. ylu@chem.ecnu.edu.cn.
Abstract:
A monolithic Ni-foam@PdNi(alloy) catalyst is tailored for coalbed methane deoxygenation via galvanically depositing Pd nanoparticles on a Ni-foam surface followed by in situ activation. Experimental and theoretical studies unanimously reveal that the in situ formed PdNi alloy contributes to high activity/selectivity, good stability and oscillation elimination.


