Related Experiment Video
Updated: Apr 7, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Zeroth law and nonequilibrium thermodynamics for steady states in contact
Sayani Chatterjee1, Punyabrata Pradhan1, P K Mohanty2,3
1Department of Theoretical Sciences, S. N. Bose National Centre for Basic Sciences, Kolkata 700098, India.
Abstract:
We ask what happens when two nonequilibrium systems in steady state are kept in contact and allowed to exchange a quantity, say mass, which is conserved in the combined system. Will the systems eventually evolve to a new stationary state where a certain intensive thermodynamic variable, like equilibrium chemical potential, equalizes following the zeroth law of thermodynamics and, if so, under what conditions is it possible? We argue that an equilibriumlike thermodynamic structure can be extended to nonequilibrium steady states having short-ranged spatial correlations, provided that the systems interact weakly to exchange mass with rates satisfying a balance condition-reminiscent of a detailed balance condition in equilibrium. The short-ranged correlations would lead to subsystem factorization on a coarse-grained level and the balance condition ensures both equalization of an intensive thermodynamic variable as well as ensemble equivalence, which are crucial for construction of a well-defined nonequilibrium thermodynamics. This proposition is proved and demonstrated in various conserved-mass transport processes having nonzero spatial correlations.
Related Concept Videos
Zeroth Law of Thermodynamics
The Zeroth Law of Thermodynamics
Thermodynamic Systems
Consider an example of tea boiling in a kettle. The...
Entropy and the Second Law of Thermodynamics
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
Entropy and the Second Law of Thermodynamics
Limits of the First Law of Thermodynamics

