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Updated: Apr 7, 2026

Observation and Analysis of Blinking Surface-enhanced Raman Scattering
Published on: January 11, 2018
Spectroscopic signatures of an ordered array of independent Ag heptamers
P Moras1, P M Sheverdyaeva, D Pacilé
1Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche, Trieste, Italy.
Abstract:
A periodic network of Ag heptamers forms on the carburized W(1 1 0)-R(15 × 12) surface, upon deposition of sub-monolayer amounts of Ag. We investigate the electronic structure and dimensionality of this system by angle-resolved photoemission spectroscopy. The observation of very well-defined Ag 4d-levels confirms the highly ordered growth of size-selected Ag nano-particles on the W(1 1 0)-R(15 × 12) template. The absence of energy dispersion of these states indicates negligible coupling among the Ag heptamers, and points out the local character of the heptamer-substrate interaction. The system can be described as an array of Ag heptamers with fully confined Ag 4d-levels.
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