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Updated: Apr 7, 2026

Preparation, Purification, and Characterization of Lanthanide Complexes for Use as Contrast Agents for Magnetic Resonance Imaging
Published on: July 21, 2011
A Highly Triflated Rare-Earth Ion in [Eu(O3SCF3)8](5-)
Jörn Bruns1, Sascha Krüger2, Matthias Adlung2
1Carl von Ossietzky Universität Oldenburg, Institut für Chemie, Carl-von-Ossietzky Strasse 9-11, 26129 Oldenburg (Germany), Fax: (+49) 441-798-3352.
Abstract:
The reaction of Eu2O3 with fuming nitric acid, trifluormethanesulfonic acid, and its anhydride in torch-sealed glass ampoules at 120 °C gave the europium compound (NO)5[Eu(O3SCF3)8] (orthorhombic, Fddd, Z = 16, a = 1932.69(4), b = 2878.44(7), c = 2955.12(7) pm, V = 16439.7(7) Å(3)). The compound exhibits the [Eu(O3SCF3)8](5-) anion showing for the first time a lanthanide ion that is exclusively coordinated by eight triflate anions. The anion has been further investigated by DFT calculations, which also allowed clear assignment of the vibrational spectra. Moreover, magnetochemical and luminescence measurements gave additional insight into the properties of this complex. The luminescence spectra revealed that the Eu(3+) ions are in a pseudo D4d symmetric environment.
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