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A Molecular Diode with a Statistically Robust Rectification Ratio of Three Orders of Magnitude
Li Yuan1, Rochus Breuer2, Li Jiang1
1†Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543.
Abstract:
This paper describes a molecular diode with high, statistically robust, rectification ratios R of 1.1 × 10(3). These diodes operate with a new mechanism of charge transport based on sequential tunneling involving both the HOMO and HOMO-1 positioned asymmetrically inside the junction. In addition, the diodes are stable and withstand voltage cycling for 1500 times, and the yield in working junctions is 90%.
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