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Solvent-dependent intramolecular charge transfer delocalization/localization in multibranched push-pull chromophores

Yang Li1, Meng Zhou1, Yingli Niu1

  • 1Beijing National Laboratory for Molecular Sciences (BNLMS) and Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.

The Journal of Chemical Physics
|July 24, 2015
PubMed
Summary

Solvent polarity dictates excitation delocalization in multibranched push-pull chromophores. In less polar solvents, excitation spreads across all branches; in more polar solvents, it localizes on one branch.

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