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Charge-Induced Second-Harmonic Generation in Bilayer WSe2.

Huakang Yu1, Deep Talukdar1, Weigao Xu1

  • 1†Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371 Singapore.

Nano Letters
|July 24, 2015
PubMed
Summary

Researchers discovered charge-induced second-harmonic generation (SHG) in 2D WSe2 bilayers. This new phenomenon, CHISHG, arises from charge accumulation and offers insights into low-dimensional electronic devices.

Keywords:
Charged-induced second-harmonic generationbond charge modelcharge accumulationscreening effecttungsten diselenidetwo-dimensional layered materials

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Optoelectronics

Background:

  • Nonlinear light-matter interactions are crucial for fundamental science and optoelectronics.
  • Two-dimensional (2D) crystals offer novel ways to electrically control nonlinear optical processes.

Purpose of the Study:

  • To investigate and report strong second-harmonic generation (SHG) in a 2D WSe2 bilayer crystal.
  • To understand the mechanism behind gate-field-induced SHG in 2D materials.

Main Methods:

  • Experimental application of a back gate field to a 2D WSe2 bilayer.
  • Analysis using a bond-charge model to elucidate the origin of SHG.
  • Characterization of charge accumulation and depletion effects.

Main Results:

  • Observed strong SHG in 2D WSe2 bilayer exclusively under charge accumulation conditions.
  • Identified the origin of SHG to be nonuniform electric field distribution within a monolayer due to screening charge.
  • Coined the term "charge-induced SHG" (CHISHG) for this distinct phenomenon.

Conclusions:

  • CHISHG is fundamentally different from previously known field- or current-induced SHG.
  • This finding introduces a valuable technique for noninvasive probing of charge and current distributions in 2D electronic devices.