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Polymer Classification: Stereospecificity01:26

Polymer Classification: Stereospecificity

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Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Polymerization stress--is it clinically meaningful?

Jack L Ferracane1, Thomas J Hilton1

  • 1Department of Restorative Dentistry, Oregon Health & Science University, Portland, OR 97201, USA.

Dental Materials : Official Publication of the Academy of Dental Materials
|July 30, 2015
PubMed
Summary
This summary is machine-generated.

Polymerization shrinkage stress in dental composites is well-documented, with known negative effects. While direct clinical proof is limited, its clinical relevance is significant for restorative dentistry.

Keywords:
ClinicalContraction stressDental compositePolymerization shrinkageProperties

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Area of Science:

  • Dental Materials Science
  • Biomaterials Engineering
  • Clinical Dentistry

Background:

  • Dental composite restoratives are widely used.
  • Polymerization shrinkage and resulting stress are inherent properties of these materials.
  • Understanding these phenomena is crucial for clinical success.

Purpose of the Study:

  • To review the evidence for polymerization shrinkage and shrinkage stress in dental composites.
  • To evaluate the clinical relevance of these stresses in restorative dentistry.

Main Methods:

  • A literature review of articles on polymerization contraction stress in dental composites.
  • Inclusion of studies focusing on factors influencing stress generation.
  • Emphasis on evidence derived from clinical studies and systematic reviews.

Main Results:

  • Extensive evidence confirms polymerization contraction stress in dental composites.
  • Deleterious effects include marginal leakage, gap formation, and reduced mechanical properties.
  • Direct clinical evidence linking stress to outcomes like sensitivity or recurrent caries is limited.

Conclusions:

  • While direct clinical proof of reduced longevity due to contraction stress is lacking, indirect evidence is substantial.
  • The significant concern and efforts to control these stresses highlight their clinical relevance in dental restorations.