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Hemoglobin-mediated synthesis of PEDOT:PSS: enhancing conductivity through biological oxidants
J D Morris1, D Khanal, J A Richey
1School of Science and Technology, Georgia Gwinnett College, Lawrenceville, Georgia 30043, USA.
Abstract:
Hemoglobin- and catalase-polymerized
Pedot:
PSS were characterized by X-ray photoelectron spectroscopy, visible and near-IR spectroscopy, FTIR, and ESR. Hemoglobin-polymerized
Pedot:
PSS possesses bipolarons, while catalase-polymerized
Pedot:
PSS is dominated by polarons. Use of heme-bound iron as an oxidant yields
Pedot:
PSS with conductivity of 19.5 S cm(-1) in a single-step aqueous reaction.
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