Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

6.7K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
6.7K
Susceptibility, Permittivity and Dielectric Constant01:26

Susceptibility, Permittivity and Dielectric Constant

3.5K
When placed in an external electric field, a dielectric material gets polarized. The charge density in the dielectric material is given by the sum of the bound and free charge densities, while the total charge density can also be written in terms of the total electric field. The bound charge density can be measured in terms of polarization, leading to the relationship between electric displacement and polarization.
3.5K
Debye–Huckel–Onsager Conductance Equation01:28

Debye–Huckel–Onsager Conductance Equation

219
The Debye-Hückel-Onsager equation is a cornerstone of physical chemistry, providing a method to determine the molar conductance (Λm) and molar conductance at infinite dilution (Λ°m) for uni-univalent electrolytes.Uni-univalent electrolytes are electrolytes that dissociate in solution to produce one cation with a +1 charge and one anion with a –1 charge per formula unit.This equation addresses two crucial phenomena: the asymmetry effect and the electrophoretic effect.
219
Electrostatic Boundary Conditions in Dielectrics01:27

Electrostatic Boundary Conditions in Dielectrics

2.1K
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity....
2.1K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Strong field quantum control of bimolecular reactions.

The Journal of chemical physics·2025
Same author

33 Unresolved Questions in Nanoscience and Nanotechnology.

ACS nano·2025
Same author

Alignment Thresholds of Molecules.

Physical review letters·2022
Same author

Interplays of electron and nuclear motions along CO dissociation trajectory in myoglobin revealed by ultrafast X-rays and quantum dynamics calculations.

Proceedings of the National Academy of Sciences of the United States of America·2021
Same author

Light-Triggered Switching of Quantum Dot Photoluminescence through Excited-State Electron Transfer to Surface-Bound Photochromic Molecules.

Nano letters·2021
Same author

Photoisomerization-coupled electron transfer.

The Journal of chemical physics·2020
Same journal

Electronegative, Transparent, and Flexible Triboelectric Electrodes via Three-Dimensionally Stacked Interconnect Structure with Cross-Interface Electron Transport.

The journal of physical chemistry letters·2026
Same journal

Effects of Ether Bonds on Liquid-Liquid Transitions in Quaternary Ammonium and Phosphonium Ionic Liquids under High Pressure.

The journal of physical chemistry letters·2026
Same journal

Origins of Size-Dependent Kinetics in Microdroplets.

The journal of physical chemistry letters·2026
Same journal

Iso-Potential <i>Operando</i> Coupling of XRD and a Profile Reactor: Structural Insights into ZnPd/ZnO during Methanol Steam Reforming.

The journal of physical chemistry letters·2026
Same journal

Formation of Methanol Clathrate Hydrate in Simulated Interstellar Ices.

The journal of physical chemistry letters·2026
Same journal

Suppressing Residual Low-Dimensional Phases in Bromide Perovskite LEDs Using a Dimethyl Phosphate Ionic Liquid.

The journal of physical chemistry letters·2026
See all related articles

Related Experiment Video

Updated: Apr 5, 2026

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
10:35

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals

Published on: May 29, 2018

9.3K

Time-Dependent, Optically Controlled Dielectric Function.

Maxim Artamonov1, Tamar Seideman1

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.

The Journal of Physical Chemistry Letters
|August 12, 2015
PubMed
Summary
This summary is machine-generated.

Scientists can control plasmon resonance by optically modulating the dielectric function of molecular monolayers on metal surfaces. A laser pulse temporarily aligns molecules, altering the dielectric function and influencing plasmon behavior.

Keywords:
molecular alignmentmolecular dynamicspolarizabilityself-assembled monolayersurface plasmon resonance

More Related Videos

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
09:32

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films

Published on: January 26, 2016

8.7K
Rapid Repetition Rate Fluctuation Measurement of Soliton Crystals in a Microresonator
07:42

Rapid Repetition Rate Fluctuation Measurement of Soliton Crystals in a Microresonator

Published on: December 15, 2021

3.6K

Related Experiment Videos

Last Updated: Apr 5, 2026

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
10:35

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals

Published on: May 29, 2018

9.3K
Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
09:32

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films

Published on: January 26, 2016

8.7K
Rapid Repetition Rate Fluctuation Measurement of Soliton Crystals in a Microresonator
07:42

Rapid Repetition Rate Fluctuation Measurement of Soliton Crystals in a Microresonator

Published on: December 15, 2021

3.6K

Area of Science:

  • Surface science
  • Plasmonics
  • Molecular electronics

Background:

  • Plasmon resonance phenomena are crucial in various optical applications.
  • Controlling these phenomena at the molecular level is an ongoing challenge.

Purpose of the Study:

  • To propose and investigate optical modulation of a molecular monolayer's dielectric function.
  • To demonstrate a method for controlling plasmon resonance phenomena.

Main Methods:

  • Utilizing a laser pulse with moderate intensity and linear polarization.
  • Employing molecular dynamics calculations to simulate time-dependent dielectric function changes.

Main Results:

  • Demonstrated that optical modulation can alter the dielectric function of a molecular monolayer.
  • Showcased the temporary alignment of molecules by the laser pulse.
  • Confirmed the monolayer returns to its initial state post-pulse.

Conclusions:

  • Optical modulation of dielectric function offers a viable route to control plasmon resonance.
  • This technique provides a dynamic and reversible method for manipulating surface plasmons.