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Strain-Induced Segregation in Bimetallic Multiply Twinned Particles
Lingxuan Peng1, Richard P Van Duyne1, Laurence D Marks1
1†Department of Materials Science and Engineering and ‡Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.
Abstract:
We analyze the possibility of strain-induced segregation in bimetallic multiply twinned particles by an analytic first-order expansion within a continuum model. The results indicate that while the change in free energy may be small, there will be a noticeable segregation of larger atoms to the external surface and smaller ones to the core, which could have interesting effects when such nanoparticles are used as heterogeneous catalysts.
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