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Strain-Induced Segregation in Bimetallic Multiply Twinned Particles
Lingxuan Peng1, Richard P Van Duyne1, Laurence D Marks1
1†Department of Materials Science and Engineering and ‡Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.
Strain-induced segregation occurs in bimetallic nanoparticles. Larger atoms migrate to the surface, and smaller atoms to the core, impacting their catalytic properties.
Area of Science:
- Materials Science
- Nanotechnology
- Chemical Engineering
Background:
- Bimetallic nanoparticles are crucial in heterogeneous catalysis.
- Understanding atomic behavior within nanoparticles is key to optimizing catalyst performance.
- Multiply twinned particles (MTPs) exhibit unique structural properties.
Purpose of the Study:
- To investigate strain-induced atomic segregation in bimetallic MTPs.
- To determine the distribution of atoms within these nanoparticles under strain.
- To explore the implications of this segregation for catalytic applications.
Main Methods:
- Utilized an analytic first-order expansion.
- Employed a continuum model for analysis.
- Focused on bimetallic multiply twinned particles.
Main Results:
- Identified a tendency for strain-induced segregation.
- Observed segregation of larger atoms to the external surface.
- Observed segregation of smaller atoms to the core.
Conclusions:
- Strain-induced segregation is a notable phenomenon in bimetallic MTPs.
- This atomic redistribution can influence nanoparticle properties.
- The findings suggest potential for tuning heterogeneous catalysts through controlled segregation.
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