Related Experiment Video
Updated: Apr 5, 2026
Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model
Published on: August 22, 2015
Solution Synthesis and Optical Properties of Transition-Metal-Doped Silicon Nanocrystals
Benjamin F P McVey1,2, Justinas Butkus1, Jonathan E Halpert1
1†School of Chemical and Physical Sciences and the MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, Wellington 6012, New Zealand.
Abstract:
A new synthetic method was developed to produce a range of transition-metal (Mn, Ni, and Cu) doped silicon nanocrystals (Si NCs). The synthesis produces monodisperse undoped and doped Si NCs with comparable average sizes as shown by transmission electron microscopy (TEM). Dopant composition was confirmed by EDX (energy dispersive X-ray spectroscopy). The optical properties of undoped and doped were compared and contrasted using absorption (steady-state and transient) and photoluminescence spectroscopy. Doped Si NCs demonstrated unique dopant-dependent optical properties compared to undoped Si NCs such as enhanced subgap absorption, and 40 nm shifts in the emission. Transient absorption (TA) measurements showed that photoexcitations in doped Si NCs relaxed via dopant states not present in undoped Si NCs.
