Related Experiment Video
Updated: Apr 5, 2026
Resonance Fluorescence of an InGaAs Quantum Dot in a Planar Cavity Using Orthogonal Excitation and Detection
Published on: October 13, 2017
Bound 1D Excitons in Single CdSe Quantum Wires
Virginia L Wayman1, Paul J Morrison1, Fudong Wang1
1Department of Chemistry and Center for Materials Innovation, Washington University, One Brookings Drive, CB 1134, Saint Louis, Missouri 63130, United States.
Abstract:
Photogenerated electron-hole pairs are observed to be bound as 1D excitons in CdSe quantum wires (QWs) at room temperature. Microscopy experiments performed on dilute samples of CdSe QWs prepared on coverslips with patterned electrodes reveal that there is no change in either the overall photoluminescence (PL) intensity or the distribution of the PL intensity with the application of an external electric field. Changes in the PL intensity, and thus evidence for separate charge carriers within the QWs, are observed only for concentrated samples. In these concentrated samples, a thin film of other compounds, including trioctylphosphine oxide and a bismuth salt formed in the synthesis, is observed to encompass the QWs. The separate charge carriers that influence the PL intensity are attributed to the other compounds in the sample.
Related Concept Videos
02:42Valence Bond Theory
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
01:01Energy Bands in Solids
Band Formation:
When atoms are brought close together, as in a solid, these discrete energy levels begin to split due to the overlap of electron orbitals from adjacent atoms. This split occurs because of the Pauli exclusion principle, which states...