Fluorinated noble-gas cyanides FKrCN, FXeCN, and FXeNC
Cheng Zhu1, Markku Räsänen1, Leonid Khriachtchev1
1Department of Chemistry, University of Helsinki, P.O. Box 55, FI-00014 Helsinki, Finland.
Abstract:
We report on three new noble-gas molecules, FKrCN, FXeCN, and FXeNC, prepared in low-temperature Kr and Xe matrices. These molecules are made by UV photolysis of FCN in the matrices and subsequent thermal annealing. The FCN precursor is produced by deposition of the matrix gas containing (FCN)3 through a microwave discharge. The new noble-gas molecules are assigned with the help of quantum chemical calculations at the MP2(full) and CCSD(T) levels of theory. Similar Ar compounds (FArCN and FArNC) as well as FKrNC are not found in these experiments, which is in agreement with the calculated energetics.
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