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Hierarchical carbon framework wrapped Na3V2(PO4)3 as a superior high-rate and extended lifespan cathode for
Yongjin Fang1, Lifen Xiao2, Xinping Ai1
1College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources, Wuhan University, Wuhan, 430072, China.
Abstract:
Hierarchical carbon framework wrapped Na3 V2 (PO4 )3 (HCF-NVP) is successfully synthesized through chemical vapor deposition on pure Na3 V2 (PO4 )3 particles. Electrochemical experiments show that the HCF-NVP electrode can deliver a large reversible capacity (115 mA h g(-1) at 0.2 C), superior high-rate rate capability (38 mA h g(-1) at 500 C), and ultra-long cycling stability (54% capacity retention after 20 000 cycles).
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