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A Continuous-flow Photocatalytic Reactor for the Precisely Controlled Deposition of Metallic Nanoparticles
Published on: April 10, 2019
Investigation on graphene and Pt co-modified CdS nanowires with enhanced photocatalytic hydrogen evolution activity
Muhan Cao1, Peifang Wang, Yanhui Ao
1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing, 210098, China. andyao@hhu.edu.cn.
Abstract:
Hydrogen evolution by photocatalytic water splitting has attracted extensive attention in recent years. Here we report a composite photocatalyst, in which graphene and Pt particles act as cocatalysts to modify CdS nanowires. This composite photocatalyst was prepared by a solvothermal method followed by a photoreduction process. The obtained samples were characterized by X-ray powder diffraction, UV-vis diffuse reflectance spectroscopy, scanning and transmission electron microscopy, X-ray photoelectron spectroscopy, photoluminescence and Brunauer-Emmett-Teller specific surface area analysis. The graphene and Pt comodified CdS nanowires gain a high hydrogen evolution rate of 3984 μmol h(-1) g(-1), which is almost 4 times higher than that of bare CdS nanowires and also higher than the sum of graphene-CdS and Pt-CdS nanowires. The obtained sample also exhibits a good stability. The encouraging results presented here can be attributed to the incorporation of graphene and Pt which show a synergetic effect for hydrogen evolution. This work paves a way to the potential application of CdS nanowires in energy conversion.

