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Published on: October 11, 2016
Corrosion inhibition property of polyester-groundnut shell biodegradable composite
P Sounthari1, A Kiruthika1, J Saranya1
1Department of Chemistry, P.S.G.R. Krishnammal College for Women, Peelamedu, Coimbatore 641004, Tamil Nadu, India.
This study reveals that polyester-groundnut shell composites effectively inhibit mild steel corrosion in acidic solutions. The composite forms a protective film on the steel surface, with efficiency increasing with concentration and decreasing with temperature.
Area of Science:
- Materials Science
- Corrosion Science
- Polymer Chemistry
Background:
- Natural fibers offer environmental benefits in composite materials.
- Groundnut shell (GNS) waste can be utilized in polymer composites.
- Corrosion inhibition is crucial for material longevity.
Purpose of the Study:
- To investigate the corrosion inhibition properties of a polyester-groundnut shell composite (PEGNS).
- To evaluate the effectiveness of PEGNS as a corrosion inhibitor for mild steel in 1M H2SO4.
- To understand the mechanism of corrosion inhibition by PEGNS.
Main Methods:
- Polyester (PE) synthesis via condensation polymerization.
- PEGNS composite preparation using ultrasonication.
- Material characterization using FT-IR, TGA, and XRD.
- Corrosion inhibition evaluation via gravimetric, electrochemical (EIS, polarization), AAS, and SEM methods.
Main Results:
- PEGNS demonstrated significant corrosion inhibition for mild steel in 1M H2SO4.
- Inhibition efficiency increased with PEGNS concentration and decreased with temperature.
- Adsorption followed the Langmuir isotherm, indicating protective film formation.
- Electrochemical parameters confirmed PEGNS adsorption on the mild steel surface.
Conclusions:
- PEGNS is an effective, eco-friendly corrosion inhibitor for mild steel.
- The composite functions by adsorbing onto the metal surface, forming a protective layer.
- This research highlights the potential of waste materials in developing functional composites.
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